ADVANCED TOPICS IN PHYSICAL CHEMISTRY - 2017/8
Module code: CHEM027
CARTA D Dr (Chemistry)
Number of Credits
FHEQ Level 7
Module cap (Maximum number of students)
Overall student workload
Independent Study Hours: 116
Lecture Hours: 30
Tutorial Hours: 4
|Assessment type||Unit of assessment||Weighting|
|Examination||EXAM - 2 HOURS||70|
Prerequisites / Co-requisites
A knowledge of Physical Chemistry to FHEQ Level 5 and 6.
This module is a research-informed FHEQ level 7 course that builds on levels 4-6 to inform, analyse and stimulate enquiry into current Advanced Physical Chemistry research in problems of relevance to industry and the environment. It features green chemistry, catalysis, surface science, nanomaterials and photochemistry.
To apply chemical kinetics in environmental and catalytic chemistry, including relevant parts of surface science
To apply advanced spectroscopic techniques to chemically relevant problems.
To apply photochemical excitation and decay processes to molecules.
To understand structure, properties and applications of nanomaterials.
To understand some fundamental applications of computational chemistry.
|001||Evaluate and give a detailed and critical account of the kinetics of physical processes in green, atmospheric and catalytic chemistry;||KC|
|002||Evaluate and give a detailed and critical account of the applications of and advances in the area of surface science||KC|
|003||Evaluate and give a detailed and critical account of aspects of advanced spectroscopic techniques||KC|
|004||Explain and give a detailed and critical account of the processes involved in photochemistry and the excitation of molecules by photons.||KC|
|005||Explain and give a detailed and critical account of processes involving nanomaterial preparation||KC|
|006||Explain and give a critical account of different computational chemistry methods||KC|
C - Cognitive/analytical
K - Subject knowledge
T - Transferable skills
P - Professional/Practical skills
Indicative content includes:
Green, Atmospheric and Catalyst Chemistry
The twelve principles of green chemistry; photochemistry and kinetics of green chemistry; photoelectrolysis and photocatalysis.
Atmospheric reactions and pollution; air pollution control kinetics; kinetics of consecutive reactions, greenhouse gases.
Solids (metallic, ionic and molecular). Surfaces. Surface crystallography: X-ray based spectroscopic techniques.
Physical adsorption, capillary condensation and catastrophes. Chemisorption and sticking probabilities. Thermodynamic parameters. Langmuir isotherm. Lindemann-Hinshelwood, Langmuir-Hinshelwood and Eley-Rideal mechanisms. Heterogeneous catalysis in process, food, environmental of forensic chemistry. Homogeneous catalysis. Enzymic catalysis
Synthesis: bottom-up and top-down approaches. Zero-dimensional nanostructures: nanoparticles. One-dimensional nanostructures: nanowires and nanotubes. Carbon nanotubes synthesis, characterisation and applications. Two-dimensional nanostructures: thin films. Physical and chemical vapour deposition, atomic layer deposition. Porous nanomaterials. Sol-gel synthesis of mesoporous silica. Surface area determination and pore analysis using gas adsorption
Fundamentals of Computational Chemistry for Chemists
Molecular Dynamics, Hartree-Fock Theory, Thomas-Fermi Theory, Kohn-Sham DFT, dispersion-corrected DFT, QM/MM
Beer-Lambert Law and adsorption strengths; Frank-Condon principle; fates of photochemically excited molecules; fluorescence; phosphorescence; internal conversion’ intersystem crossing; Jabblonski Diagrams; Quantum yields, fluorescence lifetimes and ‘natural lifetimes’, quenching; Stern-Volmer equation; delayed fluorescence; Fermi’s golden rule and intermolecular processes.Photochemistry and Kinetics.
Methods of Teaching / Learning
The learning and teaching strategy is designed to:
Build on the foundation of Physical Chemistry from levels 4-6 to be able to apply Physical Chemistry knowledge and reasoning to areas of topical, industrial and societal importance, including current research.
The learning and teaching methods include:
30 Formal lectures of 1hr, normally 3 per week, and coursework based on workshops
Four whole class workshops
Lectures will include discussion and interaction where appropriate. Course material will be provided on SurreyLearn, including calculational tools.
The assessment strategy is designed to provide students with the opportunity to demonstrate:
• Coursework: research, analysis and quantitative skills of all aspects of advanced physical chemistry topics taught in the module [LOs 1-4]
• Examination: understanding, analysis and recall [LOs 1-4]
Thus, the summative assessment for this module consists of:
• Coursework 1: Problem solving questions based on the material from the first half of the course (Deadline Week 7) [LOs assessed 1, 2, 3]
• Coursework 1: Problem solving questions based on the material from the second half of the course (Deadline Week 11) [LOs assessed 3, 4]
• Written unseen exam (2 hours) 70% [LOs assessed: aspects of LOs not already assessed in the coursework]
Formative assessment and feedback
Formative assessment and feedback are provided throughout the module in the form of in-class exercises, examples and worked problems. Feedback is instant as model answers (full worked solutions) are given in class. Formative assessment is also evident through the provision of ‘checklists’ at the end of each section of the module that detail the areas covered in that part of the course. Detailed and individualised feedback is given on the marked assignments within the time allowed for marking coursework.
Reading list for ADVANCED TOPICS IN PHYSICAL CHEMISTRY : http://aspire.surrey.ac.uk/modules/chem027
Programmes this module appears in
|Chemistry with Forensic Investigation MChem||2||Optional||A weighted aggregate mark of 50% is required to pass the module|
|Chemistry MChem||2||Compulsory||A weighted aggregate mark of 50% is required to pass the module|
|Chemistry MRes||2||Optional||A weighted aggregate mark of 50% is required to pass the module|
|Medicinal Chemistry MChem||2||Optional||A weighted aggregate mark of 50% is required to pass the module|
Please note that the information detailed within this record is accurate at the time of publishing and may be subject to change. This record contains information for the most up to date version of the programme / module for the 2017/8 academic year.